4-Cyano-N-ethylspiro[chromene-2,4′-piperidine]-1′-carboxamide

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4-Cyano-N-ethyl­spiro­[chromene-2,4′-piperidine]-1′-carboxamide

The title compound, C17H19N3O2, crystallizes with two independent mol-ecules (A and B) in the asymmetric unit. In both mol-ecules, the pyran ring has a twisted conformation ((5)S4), with Q = 0.301 (3) Å, θ = 116.7 (6) and ϕ= 213.6 (7)° for mol-ecule A, and Q = 0.364 (2) Å, θ = 113.7 (3) and ϕ = 213.0 (4)° for mol-ecule B. In mol-ecule B, the terminal ethyl group is disordered over two orientati...

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In the title compound, C(11)H(7)Cl(3)N(3)O, the dihedral angle between the benzene and cyclo-propane rings is 85.8 (2)°. In the crystal, mol-ecules are linked by C-H⋯O inter-actions, generating C(5) chains propagating in the a-axis direction.

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N-(4-Chloro­phen­yl)-4-methyl­piperazine-1-carboxamide

In the title compound, C(12)H(16)ClN(3)O, the piperazine ring has a chair conformation. Within this ring, the N-methyl nitro-gen atom has a pyramidal geometry and the N-carboxamide nitro-gen atom is almost planar (bond-angle sum = 359.8°). In the crystal, the mol-ecules are linked by N-H⋯O hydrogen bonds into C(4) chains propagating in [010].

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N-(4-Chloro­phen­yl)-4-ethyl­piperazine-1-carboxamide

In the title mol-ecule, C(13)H(18)ClN(3)O, the piperazine ring has a chair conformation. In the crystal, mol-ecules are linked into chains along [100] by N-H⋯O hydrogen bonds.

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N-(4-Chloro­phen­yl)-4-methyl­piperidine-1-carboxamide

In the title compound, C(13)H(17)ClN(2)O, the piperidine ring adopts a chair conformation and the N atom in that ring is close to pyramidal (bond angle sum = 357.5°). In the crystal, mol-ecules are linked into C(4) chains propagating in [010] by N-H⋯O hydrogen bonds.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812051124